I honestly don't believe that Psilocybin or Psilocyn, even if Freebase, could feesibly be smoked. I have certainly never heard of it being accomplished. From what I have heard the heat it would take to vaporize either would also be enough to destroy the compound. Ive been doing Hallucinogens over half of my life, if it were possible, I'm pretty sure I would have heard of it by now.