Not sure how it will work with toad venom. Provided you have an alkaloid mix (NN = N,N-DMT, MEO = 5-MeO-DMT, HO = 5-HO-DMT), separating them using solvents is a two-step process:
To separate NN from MEO and HO:
1. dissolve alks in acetone
2. add saturated citric acid solution (MEO,HO will precipitate, NN will dissolve)
3. filter to separate the NN from MEO,HO
4. dry and convert the citrates to freebase
To further separate MEO from HO:
1. dissolve alks in naphtha, heptane, xylene or d-limonene
2. mix, wait until the alks settle, filter
3. scrape HO from filter
4. evaporate solvent to get MEO
Source: SWIM's Psychedelic Cookbook, pp. 128-129