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Ammonium hydroxide vs. Sodium hydroxide - what is better?

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For the final extraction step (transform alkaloids to free base, see STEP 8: Erowid DMT Vaults : Extraction : QT's DMT Extraction Guide ) Ammonium hydroxide or Sodium hydroxide (NaOH) can be used interchangeably.

My concern is that NaOH may not evaporate but remain as salt in the DMT crystals, and it would be toxic to inhale it. Is this true?
Besides, Red Devil drain cleaner is not available for purchase anymore.

Alternatively, Ammonium hydroxide does evaporate. And you can purchase the solution easily, e.g. here: http://tinyurl.com/ammonia1

Thus, what is better (less toxic): NaOH or Ammonium hydroxide?
 
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