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I’m new so hopefully I asked my question correctly Can the acid stage get to hot? It was almost boiling.

What are you trying to extract and how? If DMT then you're fine as the salt is stable well above boiling. As for other alkaloids then I defer to my more learned friends here :)
 
100g Illinois bundle flower 1/2 cup vinegar 2cups distilled water
Half a cup of vinegar is unnecessary.. you only need a ph of around 4. Measuring water isn't necessary either, but you aren't using enough for 100g of material IMO. Dilution is your friend in the initial boils. If you only use a tiny amount you'll end up with some of your alkaloids trapped in your plant material as it will hold some of your solution. Dilute it more and you won't have this issue. Then you can just reduce your solution to a workable volume after your boils.
 
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