The 24hr wait is not needed for the first few pulls, only the last pull should one leave it in for 24hrs, when there is less spice in the soup. Give it a roll every now and then during the 24hrs to get all the goodies out in the last pull.
I usually wait 2 days for the first pull with an STB and when I add my first pull I agitate it periodically for 24 hours. This is because I like a very sturated solvent so I can do a slow freeze precip for nice crystals first time round.
I do much less pulls this way, but I'm also never in a hurry.
Of course though with an A/B I pull quite soon after the mix is based.
With A/B (using lime) SWIM has never seen a difference between pulling for 15 minutes vs 30 minutes
This is assuming the DMT is freebased already which with an A/B is in a few hours while a STB takes a few days.
It's not like leaching and breaking down plants in ethanol, the naptha is just dissolving the DMT like table salt dissolving in water.
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