Please note that there are hundreds of Acacia species so I could very well be mistaken, but your photo very much looks like Acacia longifolia (which is a dud as for DMT)
However it could also be Acacia obtusiflia, although its a bit rarer. A. Obtusifolia is reputedly one of the best DMT sources.
Check the leaf margins and the flowering period for a positive ID.
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