Had the exact same problem with Cyb's teks. Add a spoonful of lye and heat it up, shake, and settle. I've also tried adding some extra salt, which doesn't seem to hurt. That should help a lot. Repeat if necessary until you're happy with how much naphtha you can get.
And in worst case scenario you can suck it up with a Turkey baster and poor the top layer into another bottle and add more water and it will separate eventually. Thus you can still continue working with the original vessel.
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