Edited post:
I'd like to buy a book for understanding more.
Personal don't like to read before a monitor, when it is complex.
I'm looking for a understanding of what is happening and why on Extractions in detail.
Is the book suiting or what topics in a book I should look for?
I'm not sure if the book is maybe to much or way to specific if no pre requirements are met
What you think of this one
Buy Organische Chemie: für Biochemiker, Lebenswissenschaftler, Mediziner, Pharmazeuten... (Verdammt clever!) (German Edition): Read Kindle Store Reviews - Amazon.com
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I translated the index?
Table of Contents
Preface 1 X
Abbreviations 1 I
1 Bonding Concepts in Organic Chemistry 1
1.1 Hybridization 1
1.2 The Covalent Bond 5
1.2.1 The Single Bond 6
1.2.2 The Double Bond 7
1.2.3 The Triple Bond 9
2 Fundamentals of Organic Chemistry 11
2.1 Spatial Representation 11
2.1.1 The Fischer Projection 13
2.1.2 The Newman Projection 15
2.1.3 The Sawhorse Projection 15
2.1.4 The Haworth Projection 15
2.2 Structure 17
2.2.1 Configuration and Conformation 17
2.2.2 Isomerism 20
2.2.3 Tautomerism 23
2.3 Stability 24 2.3.1 The Carbenium Ion 2 5
2.3.2 The Carbanion 26
2.3.3 The Erlenmeyer Rule 28
2.3.4 Ring Strain 29
2.4 Catalysts in Organic Chemistry 30
2.4.1 Organometallic Catalysts 31
2.4.2 Stoichiometric Additives (Accelerators, Mediators)
3 Aromaticity and Heteroaromaticity 33
3.1 Delocalization, Mesomerism, Aromaticity 33
3.2 Second Substitution on Aromatics 4 2
VI I Table of Contents
3.2.1 Inductive Effect 43
3.2.2 Mesomeric Effect 45
3.3 Annealed Systems 46
3.4 Heteroaromatics 51
3.4.1 Electron-rich heteroaromatics 52
3.4.2 Electron-poor heteroaromatics 55
3.5 Nomenclature 58
3.5.1 Exchange nomenclature 63
4 Reactivity: Polarity of the covalent bond 67
4.1 Electronegativity 67
4.2 Polarity 68
4.2.1 Bond strength 70
4.2.2 Polar moment 71
4.3 Polar bonds in organic chemistry 75
4.3.1 Electrophilic centers 78
4.3.2 Nucleophilic centers 81
4.4 Hydrogen bonding 82
5 Lewis base concept: The importance of Lewis bases in organic chemistry 87
5.1 The definition of Lewis Acids and Lewis Bases 8 7
5.2 The Importance of the Lewis Base as an Electron-Rich Agent 8 9
5.3 The Action of Lewis Acids as Electrophiles 92
5.3.1 The Proton as a Lewis Acid 92
5.3.2 Lewis Acids as Mediators 95
5.4 The Leaving Group 9 7
5.5 The HSAB Concept 200
5.5.1 The Classification into Hard and Soft Acids and Bases 100
5.5.2 The Quantification of the HSAB Concept 101
6 Reaction Mechanisms in Organic Chemistry 105
6.1 Key 105
6.2 Addition 106
6.2.1 Electrophilic Addition 107 6.2.2 Nucleophilic Addition 109
6.2.3 Radical Addition 111
6.2.4 Cycloadditions 113
6.3 Substitution 114
6.3.1 Nucleophilic Substitution 115
6.3.2 Electrophilic Substitution 127
6.3.3 Radical Substitution 136
6.4 Elimination 138
6.4.1 Unimolecular Elimination: The Ei Mechanism 138
6.4.2 Bimolecular Elimination: The E2 Mechanism 139
Table of Contents IV II
6.4.3 The EjcB Mechanism of β-Elimination 140
6.4.4 Intramolecular Elimination: The E or Syn Mechanism 141
6.5 Condensation 142
6.6 Rearrangements 143
6.6.1 Pinacolum Rearrangement 143
6.6.2 Beckmann Rearrangement 143
6.6.3 Claisen Rearrangement 145
7 Functional Groups and Their Derived Reactivities 147
7.1 The Hydrocarbons 148
7.1.1 The Alkanes 148
7.1.2 The Alkenes 151
7.1.3 The Alkynes 159
7.1.4 Aromatics 160
7.1.4.1 Second Substitution 163
7.2 Halogen Compounds 168
7.3 Alcohols (Mercaptans) 174
7.4 Amines 180
7.5 Etilers (Thioethers) 187
7.6 Carbonyl Compounds 192
7.6.1 Aldehydes 193
7.6.2 Ketones 201
7.6.3 Imines 203
7.6.4 Carboxylic Acids 204
7.6.5 Carboxylic Anhydrides 208
7.6.6 Carboxylic Halides 210
7.6.7 Esters 212
7.6.8 Carboxylic Amides 213
7.7 Nitriles 215
A Overview Diagrams 219
B Glossary 221
C Correctly Solved 243
Index 263
