Hello Nexians.
I've found a local shop that has some interesting chems, and I would like to ask for some opinions on wich one should be the best among them for extraction.
The list is the following:
Cyclo-hexane
Iso-pentane
Iso-octane
Ethyl ether
N-heptane
Trichloroethylene
Ligroin
All of those are HPLC grade.
Thank you.
I'd just buy the lot
Isopentane evaporates way too easily, and diethyl ether does too, with the added hazard of forming explosive peroxides, so maybe skip those two unless you know exactly what you're doing.
Cyclohexane would be good except it has a high melting point, making it less useful for freeze precipitation - so maybe scratch that one off the list as well.
Trichloroethylene is non-flammable but also rather toxic, and wouldn't be usable for freeze precipitation either (afaik).
This gets us down to iso-octane, n-heptane and ligroin - all of which are basically naphtha; n-heptane is the classic recrystallisation solvent, and iso-octane is an ambiguous name: it could mean, as in the case of isopentane, the isomer with a branching at the end of the chain, 2-methylheptane, or it could refer to the isomer 2,2,4-trimethylpentane which is the "iso-octane" of motor spirit/petrol/gasoline and lends its name to the octane anti-knock rating system.
Finally, ligroin is a petroleum spirit mixture and you'd best check its boiling range to get a picture of its suitability for extraction: 85 - 110°C would be optimal (imho) and much above or below that would present potential issues of being too slow or too quick in evaporation, respectively. One can successfully extract DMT using medium-heavy naphtha, but it's then necessary to recrystallise the product with something more volatile, like heptane.
Incidentally, you can determine which kind of iso-octane it is by the boiling point given if there's no other, more accurate name available.
If you're planning on doing something other than DMT extraction your choice of solvent would depend on what you're exracting. Also, your choice of plant material could be of relevance too.